Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Initialising ...
Suno, Hiroya; Machida, Masahiko
RIST News, (66), p.3 - 16, 2020/10
no abstracts in English
HeAkimune, Hidetoshi*; Yamagata, Tamio*; Nakayama, Shintaro*; Arimoto, Yasushi*; Fujiwara, Mamoru; Fushimi, Kenichi*; Hara, Keigo*; Ota, Masahisa*; Shiokawa, Atsuko*; Tanaka, Masayoshi*; et al.
Physical Review C, 67(5), p.051302_1 - 051302_4, 2003/05
Times Cited Count：27 Percentile：80.32(Physics, Nuclear)no abstracts in English
Saeki, Masakatsu; Nakada, Masami; Nakamoto, Tadahiro*; ; Yamashita, Toshiyuki
Journal of Alloys and Compounds, 271-273, p.176 - 179, 1998/00
Times Cited Count：4 Percentile：39.18(Chemistry, Physical)no abstracts in English
Sasuga, Tsuneo
Koen Yoshishu, Dai-42-Kai Kobunshi Kaki Daigaku, 0, p.86 - 89, 1994/07
no abstracts in English
JAERI-M 7142, 76 Pages, 1977/07
no abstracts in English
Kusaka, Ryoji
no journal, ,
The interfaces of oil and aqueous phases in solvent extractions are the gates for metals to transfer between the two phases. It would be that something special occurs at the interfaces because extractants, which are ligand reagents that facilitate metal transfer into the oil phase by surrounding and stabilizing metals in the oil phase, are surfactants tending to form layers at the interfaces. We have investigated the interfaces of lanthanide and actinide solvent extractions using vibrational sum frequency generation spectroscopy both in homodyne and heterodyne detection methodologies. Vibrational signals of coordinating chemical groups of extractants and interfacial water OH stretch revealed molecular structures of lanthanide and actinide complexes with extractant forming at the interfaces, providing some aspects of phase transfer mechanism of lanthanide and actinide between the oil and aqueous phases.
